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題目:Advanced Concepts for Catalysis in Synthesis and Flow Chemistry
講演者:Prof. Thomas Wirth (イギリス,カーディフ大学)
Prof. Wirth(イギリス,カーディフ大学,化学科)は典型元素化合物、特にヨウ素やセレンを使った有機合成化学を精力的に展開しており、当該分野のリーダーとして活躍しております。今回の講演ではそれらの反応をマイクロリアクターへと利用する内容も含まれます。
アブストラクト:
The development of catalytic reactions based on stoichiometric reactions using selenium- and iodine-based reagents will be discussed. Novel chiral reagents and catalysts allow the easy synthesis of versatile scaffolds as synthetic building blocks as well as applications towards natural product synthesis. The contact between immiscible liquids in a microfluidic system creating segmented flow offers great potential in the study of biphasic reactions in organic chemistry with significant advantages with respect to conventional flask techniques. This can dramatically increase the reaction rate, especially when microwave irradiation, sonication or phase transfer catalysis are combined with segmentation. Metal-catalyzed sequences can also be performed advantageously in biphasic systems. Chemistry with hazardous chemicals, the synthesis of radiopharmaceuticals and the development of a micro-reactor for electrochemistry will be discussed.
(通訳なし)
講演終了後,後楽園付近で懇親会を予定しております.
連絡先:中央大学理工学部応用化学科
福澤 信一